メンバー

喜多　祐介（Yusuke Kita）

学歴

• 2002年3月

  初芝富田林高等学校 卒業

• 2006年3月

  大阪大学 工学部 応用自然科学科 卒業

• 2008年3月

  大阪大学 大学院工学研究科 応用化学専攻 修士課程 修了

学位

博士（工学）（2010年6月　大阪大学）

職歴

• 2010年7月

  大阪大学 大学院基礎工学研究科 物質創成専攻 助教

• 2016年3月

  東京工業大学
  応用セラミックス研究所
  セラミックス機能部門 助教

• 2016年4月

  東京工業大学
  科学技術創成研究院フロンティア材料研究所
  融合機能応用部門 助教

受賞歴

2013年度 有機合成化学協会DIC研究企画賞

2022年度 触媒学会奨励賞

第3回 ICAT Young Lectureship Azuma Award

専門

有機合成、触媒化学

発表論文： Journal | Review

Journal

• “Heterogeneous Low-valent Mn Catalysts for α-Alkylation of Ketones with Alcohols through Borrowing Hydrogen Methodology”,
  Yusuke Kita, Midori Kuwabara, Keigo Kamata, Michikazu Hara
  ACS Catalysis, 2022, 12, 11767-11775. (First published online: 2022/09/13)
  DOI: 10.1021/acscatal.2c03085
  
• “Primary Amine Synthesis by Hydrogen-involving Reactions over Heterogeneous Cobalt Catalysts”,
  Kahoko Kato, Dian Deng, Yusuke Kita, Keigo Kamata, Michikazu Hara
  Catalysis Science & Technology, 2022, 12 (17), 5425-5434. (First published online: 2022/07/22)
  DOI: 10.1039/D2CY00870J
  
• “A Heterogeneous Cobalt Catalyst for C-C Bond Formation by Borrowing Hydrogen Strategy”,
  Endah Suarsih, Yusuke Kita, Keigo Kamata, Michikazu Hara
  Catalysis Science & Technology, 2022, 12 (13), 4113-4117. (First published online: 2022/05/31)
  DOI: 10.1039/D2CY00724J
  
• “Effects of Ruthenium Hydride Species on Primary Amine Synthesis by Direct Amination of Alcohols over a Heterogeneous Ru Catalyst”,
  Yusuke Kita, Midori Kuwabara, Satoshi Yamadera, Keigo Kamata, Michikazu Hara
  Chemical Science, 2020, 11 (36), 9884-9890. (First published online: 2020/09/03)
  DOI: 10.1039/D0SC03858J
  Highlighted in Synfacts 2020, 16, 1460. DOI: 10.1055/s-0040-1706565
• “One-pot Reductive Amination of Carbonyl Compounds with Nitro Compounds over Ni/NiO Composite”,
  Yusuke Kita, Sayaka Kai, Lesandre Binti Supriadi Rustad, Keigo Kamata, Michikazu Hara
  RSC Advances, 2020, 10 (54), 32296-32300. (First published online: 2020/09/02)
  DOI: 10.1039/D0RA06937J
  Highlighted in Synfacts 2021, 17 (5), 0075. DOI: 10.1055/s-0040-1706566
• “One-pot Aerobic Oxidative Sulfonamidation of Aromatic Thiols with Ammonia by a Dual-functional β-MnO₂ Nanocatalyst”,
  Eri Hayashi, Yui Yamaguchi, Yusuke Kita, Keigo Kamata, Michikazu Hara
  Chemical Communications, 2020, 56 (14), 2095-2098. (First published online: 2020/01/22) Back Cover
  DOI: 10.1039/C9CC09411C
• “Benzylic C‐H Fluorination over Supported Silver Catalyst”,
  Yusuke Kita, Shunsuke Shigetani, Keigo Kamata, Michikazu Hara
  Molecular Catalysis, 2019, 475, 110463. (First published online: 2019/06/13)
  DOI: 10.1016/j.mcat.2019.110463
• “Low-temperature Reductive Amination of Carbonyl Compounds over Ru-deposited on Nb₂O₅·nH₂O”,
  Dian Deng, Yusuke Kita, Keigo Kamata, Michikazu Hara
  ACS Sustainable Chemistry & Engineering, 2019, 7 (5), 4692-4698. (First published online: 2018/12/19) Supplementary Cover
  DOI: 10.1021/acssuschemeng.8b04324
• “Electronic Effect of Ruthenium Nanoparticles on Efficient Reductive Amination of Carbonyl Compounds”,
  Tasuku Komanoya, Takashi Kinemura, Yusuke Kita, Keigo Kamata, Michikazu Hara
  Journal of the American Chemical Society, 2017, 139 (33), 11493-11499. (First published online: 2017/07/31)
  DOI: 10.1021/jacs.7b04481
  Highlighted in Synfacts 2017, 13 (11), 1209. DOI: 10.1055/s-0036-1591385
• “A Bifunctional Cerium Phosphate Catalyst for Chemoselective Acetalization”,
  Shunsuke Kanai, Ippei Nagahara, Yusuke Kita, Keigo Kamata, and Michikazu Hara
  Chemical Science, 2017, 8 (4), 3146-3153. (First published online: 2017/02/07)
  DOI: 10.1039/C6SC05642C
  Highlighted in Synfacts 2017, 13 (07), 0778. DOI: 10.1055/s-0036-1590610
• “Asymmetric Hydrogenation of 3-Amido-2-arylpyridinium Salts by Triply-chloride-bridged Dinuclear Iridium Complexes Bearing Enantiopure Diphosphine Ligands: Synthesis of Neurokinin-1 Receptor Antagonist Derivatives”,
  Atsuhiro Iimuro, Kosuke Higshida, Yusuke Kita, Kazushi Mashima,
  Advanced Synthesis & Catalysis, 2016, 358 (12), 1929-1933. (First published online: 2016/06/02)
  DOI: 10.1002/adsc.201600203
• “Chloride-Bridged Dinuclear Rhodium(III) Complexes Bearing Chiral Diphosphine Ligands: Catalyst Precursors for Asymmetric Hydrogenation of Simple Olefins”,
  Yusuke Kita, Shoji Hida, Kenya Higashihara, Himanshu Sekhar Jena, Kosuke Higashida, Kazushi Mashima,
  Angewandte Chemie International Edition, 2016, 55 (29), 8299-8303. (First published online: 2016/04/18)
  DOI: 10.1002/anie.201601748
• “Asymmetric Allylic Alkylation of β-Ketoesters with Allylic Alcohols Catalyzed by Nickel Complexes with a Chiral Diphosphine Ligand”,
  Yusuke Kita, Rahul D. Kavthe, Hiroaki Oda, Kazushi Mashima,
  Angewandte Chemie International Edition, 2016, 55 (3), 1098-1101. (First published online: 2015/12/04)
  DOI: 10.1002/anie.201508757
• “Construction of Tertiary Chiral Centers by Pd-catalyzed Asymmetric Allylic Alkylation of Prochiral Ketone Enolate Equivalents”,
  Yusuke Kita, Yoshitaka Numajiri, Noriko Okamoto, Brian M. Stoltz,,
  Tetrahedron (special issue for Prof. Jiro Tsuji), 2015, 71 (37), 6349–6353. (First published online: 2015/09/16)
  DOI: 10.1016/j.tet.2015.05.092
• “Pentacoordinated Carboxylate π-Allyl Nickel Complexes as Key Intermediates for Ni-catalyzed Direct Amination of Allylic Alcohols”,
  Yusuke Kita, Hironobu Sakaguchi, Yoichi Hoshimoto, Daisuke Nakauchi, Yasuhito Nakahara, Jean-François Carpentier, Sensuke Ogoshi, Kazushi Mashima,
  Chemistry - A European Journal, 2015, 21 (41), 13454‒13461. (First published online: 2015/08/26)
  DOI: 10.1002/chem.201502329
• “Manganese(II) Catalyzed Esterification of β-Hydroxyethylamides”,
  Yuji Nishii, Shoko Akiyama, Yusuke Kita, Kazushi Mashima,
  Synlett, 2015, 26, 1831–1834. (First published online: 2015/06/26)
  DOI: 10.1055/s-0034-1380428
• “Asymmetric Hydrogenation of Quinazolinium Salts Catalysed by Halide-bridged Dinuclear Iridium Complexes bearing Chiral Diphosphine Ligands”,
  Yusuke Kita, Kosuke Higashida, Kenta Yamaji, Atsuhiro Iimuro, Kazushi Mashima,
  Chemical Communications, 2015, 51 (21), 4380–4382. (First published online: 2015/02/13)
  DOI: 10.1039/C5CC00258C
• “Enhanced Effects of Salt Formation on Catalytic Activity and Enantioselectivity for Asymmetric Hydrogenation of Isoquinolinium Salts by Dinuclear Halide-bridged Iridium Complexes”,
  Yusuke Kita, Kenta Yamaji, Kosuke Higashida, Atsuhiro Iimuro, Sathaiah Kandula, Kazushi Mashima,
  Chemistry - A European Journal, 2015, 21 (5), 1915–1927. [Front Cover] (First published online: 2014/11/28)
  DOI: 10.1002/chem.201405408
• “Hydrogenation of Amides Catalyzed by Combined Catalytic System of Ru Complex with Zinc Salt”,
  Yusuke Kita, Takafumi Higuchi, Kazushi Mashima,
  Chemical Communications, 2014, 50 (76), 11211–11213. (First published online: 2014/08/12)
  DOI: 10.1039/C4CC04481A
• “Iridium-catalyzed Asymmetric hydrogenation of Pyridinium Salts for Constructing Multiple Stereogenic Centers on Piperidines”,
  Yusuke Kita, Atsuhiro Iimuro, Shoji Hida, Kazushi Mashima,
  Chemistry Letters, 2014, 43, 284-286. (First published online: 2013/11/09)
  DOI: 10.1246/cl.130943
• “Combined Catalytic System of Scandium Triflate and Boronic Esters for Amide Bond Cleavage”,
  Yusuke Kita, Yuji Nishii, Akihiro Onoue, Kazushi Mashima,
  Advanced Synthesis & Catalysis, 2013, 355 (17), 3391-3395. (First published online: 2013/11/13)
  DOI: 10.1002/adsc.201300819
• “Asymmetric Hydrogenation of Isoquinolinium Salts Catalyzed by Chiral Iridium Complexes: Direct Synthetic Protocol for Optically Active 1,2,3,4-Tetrahydroisoquinolines”,
  Atsuhiro Iimuro, Kenta Yamaji, Sathaiah Kandula, Takuto Nagano, Yusuke Kita, Kazushi Mashima,
  Angewandte Chemie International Edition, 2013, 52 (7), 2046-2050. (First published online: 2013/01/09)
  DOI: 10.1002/anie.201207748C
  Highlighted in Synfacts 2013, 9 (5), 530.DOI: 10.1055/s-0033-1338358
• “Additive Effects of Amines on Asymmetric Hydrogenation of Quinoxalines Catalyzed by Chiral Iridium Complexes”,
  Takuto Nagano, Atsuhiro Iimuro, Rino Schwenk, Takashi Oshima, Yusuke Kita, Antonio Togni, Kazushi Mashima,
  Chemistry - A European Journal, 2012, 18 (37), 11578-11592. (First published online: 2012/08/22)
  DOI: 10.1002/chem.201201366
• “Rhodium-catalyzed Carbon-Silicon Bond Activation for Synthesis of Benzosilole Derivatives”,
  Masahiro Onoe, Katsuaki Baba, Yoonjoo Kim, Yusuke Kita, Mamoru Tobisu, Naoto Chatani,
  Journal of the American Chemical Society, 2012, 134 (47), 19477-19488. (First published online: 2012/11/05)
  DOI: 10.1021/ja3096174
• “1,5-Migration of rhodium via C-H bond activation in catalytic decyanative silylation of nitriles”,
  Mamoru Tobisu, Junya Hasegawa, Yusuke Kita, Hirotaka Kinuta, Naoto Chatani,
  Chemical Communications, 2012, 48 (93), 11437-11439. (First published online: 2012/10/10)
  DOI: 10.1039/C2CC36601K
• “Zinc Catalyzed Amide Cleavage and Esterification of β-Hydroxyethylamides”,
  Yusuke Kita, Yuji Nishii, Takafumi Higuchi, Kazushi Mashima,
  Angewandte Chemie International Edition, 2012, 51 (10), 3958-3960. (First published online: 2012/04/20)
  DOI: 10.1002/anie.201201789
• “Novel Synthetic Approach to Arylboronates via Rhodium-Catalyzed Carbon-Cyano Bond Cleavage of Nitriles”,
  Hirotaka Kinuta, Yusuke Kita, Emmanuelle Rémond, Naoto Chatani,
  Synthesis, 2012, 44 (19), 2999-3002. (First published online: 2012/04/16)
  DOI: 10.1055/s-0031-1290370
• “Rhodium(I)-Catalyzed Borylation of Nitriles through the Cleavage of Carbon–Cyano Bonds”,
  Mamoru Tobisu, Hirotaka Kinuta, Yusuke Kita, Emmanuelle Rémond, Naoto Chatani,
  Journal of the American Chemical Society, 2012, 134 (1), 115-118. (First published online: 2011/12/13)
  DOI: 10.1021/ja2095975
• “Efficient Cyclic Carbonate Synthesis Catalyzed by Zinc Cluster under Mild Conditions”,
  Yi Yang, Yukiko Hayashi, Yuka Fujii, Takuto Nagano, Yusuke Kita, Jun Okuda, Takashi Oshima, Kazushi Mashima,
  Catalysis Science & Technoloby, 2012, 2 (3), 509-513. (First published online: 2011/10/17)
  DOI: 10.1039/C1CY00404B
• “Nickel-Catalyzed Cyclization of Difluoro-Substituted 1,6-Enynes with Organozinc Reagents Leading to Bicyclo[3.2.0]heptene Derivatives: The Stereoselective Activation of C-F Bonds”,
  Manabu Takachi, Yusuke Kita, Mamoru Tobisu, Yoshiya Fukumoto, Naoto Chatani,
  Angewandte Chemie International Edition, 2010, 49 (46), 8717-8720. (First published online: 2010/11/02)
  DOI: 10.1002/anie.201004543
• “Rhodium-Catalyzed Alkenylation of Nitriles via Silicon-Assisted C-CN Bond Cleavage”,
  Yusuke Kita, Mamoru Tobisu, Naoto Chatani,
  Organic Letters, 2010, 12 (8), 1864-1867. (First published online: 2010/03/25)
  DOI: 10.1021/ol100481h
• “Rhodium-Catalyzed Reductive Decyanation of Nitriles Using Hydrosilane as a Reducing Agent: Scope, Mechanism and Synthetic Application”,
  Mamoru Tobisu, Ryo Nakamura, Yusuke Kita, Naoto Chatani,
  Bulletin of the Korean Chemical Society (special issue for Prof. Sunggak Kim), 2010, 31 (3), 582-587. (First published online: 2010/03/20)
  ISSN 0253-2964
• “Rhodium-Catalyzed Coupling of 2-Silylphenylboronic Acid with Alkynes Leading to Benzosiloes: Catalytic Cleavage of the Carbon-Silicon Bond in Trialkylsilyl Groups“,
  Mamoru Tobisu, Masahiro Onoe, Yusuke Kita, Naoto Chatani,
  Journal of the American Chemical Society, 2009, 131 (22), 7506-7507. (First published online: 2009/05/13)
  DOI: 10.1021/ja90229782
• “Rhodium-Catalyzed Reductive Cleavage of Carbon-Cyano Bonds with Hydrosilanes: A Catalytic Protocol for Removal of Cyano Groups”,
  Mamoru Tobisu, Ryo Nakamura, Yusuke Kita, Naoto Chatani,
  Journal of the American Chemical Society, 2009, 131 (9), 3174-3175. (First published online: 2009/02/12)
  DOI: 10.1021/ja810142v
• “Rhodium-Catalyzed Silylation and Intramolecular Arylation of Nitriles via the Silicon-Assisted Cleavage of Carbon-Cyano Bonds”,
  Mamoru Tobisu, Yusuke Kita, Yusuke Ano, Naoto Chatani
  Journal of the American Chemical Society, 2008, 130 (47), 15982-15989. (First published online: 2008/10/31)
  DOI: 10.1021/ja804992n
• “Rh(I)-Catalyzed Silylation of Aryl and Alkenyl Cyanides Involving the Cleavage of C-C and Si-Si Bonds”,
  Mamoru Tobisu, Yusuke Kita, Naoto Chatani
  Journal of the American Chemical Society, 2006, 128 (25), 8152-8153. (First published online: 2006/06/07)
  DOI: 10.1021/ja062745w

Review

• 配位高分子から調製した担持コバルト触媒による還元的アミノ化反応
  喜多祐介
  触媒, 2019, 61 (2), 110.
• 酸化的"逆"エステル化反応
  喜多祐介
  化学, 2017, 72, 57-58.
• “Triply-halide-bridged Dinuclear Iridium(III) Complexes with Chiral Diphosphine Ligands as New Easy-to-handle Iridium Catalysts for Asymmetric Hydrogenation of Imines and N-Heteroaromatics”,
  Kazushi Mashima, Kosuke Higashida, Atsuhiro Iimuro, Haruki Nagae, Yusuke Kita,
  The Chemical Record, 2016, 16 (16), 2585-2594. (First published online: 2016/08/10)
  DOI: 10.1002/tcr.201600079
• 海外研究室レポート「Caltechでの研究と留学生活」
  喜多祐介
  Organometallic News, 2015, 3, 108-109.
• 炭化水素からの直接ニトリル合成
  喜多祐介
  Journal of Synthetic Organic Chemistry, 2014, 72 (8), 940-941.
• “Additive Effects on Asymmetric Hydrogenation of N-Heteroaromatics”,
  Takuto Nagano, Atsuhiro Iimuro, Kenta Yamaji, Yusuke Kita, Kazushi Mashima,
  Heterocycles, 2014, 88 (1), 103-128. (First published online: 2013/07/16)
  DOI: 10.3987/REV-13-SR(S)2
• “Rhodium catalyzed Carbon-Cyano bond Cleavage Reactions Using Organosilicon Reagents”,
  Yusuke Kita, Mamoru Tobisu, Naoto Chatani,
  Journal of Synthetic Organic Chemistry, 2010, 68 (11), 1112-1122.